Yes, you do have to remove the serpentine belt off to gain access to the A/C drive belt. First loosen the locking nut, then loosen the adjusting bolt to the tensioner pulley assembly until the belt can be removed.
RepairPal Certified shops can diagnose and repair your 2000 Chrysler Concorde. They provide transparent pricing with a minimum 12-month or 12,000-mile warranty on repairs and services.
I just got it changed myself. I problem is getting to the belt both serpentine and a/c belt. You have to go under the cars which is hard for chrysler because set to low.