On the V6 the crankshaft mark is simple. The mark on the inner edge of the crank sprocket lines up with the mark in the aluminum housing on the front of the block. The passenger side cam sprocket should be a gear that has the teeth exposed and the driver's side cam sprocket should have a guide rail build onto the edge of the gear to act as a guide for the belt. The marks then on the pulley line up with the marks on the black tin shield behind the sprockets.
Why is the camshaft being replaced, did the engine run prior to replacing the camshaft?
#1 cylinder is the passenger side front of the engine #3 and #5 also that side of the engine. #2 is driver's side front followed by #4, and #6 on that side of the engine. With #1 cylinder firing ( top of its compression stroke) valves should have clearance where is the rotor pointing in the distributor cap? That will be the easiest way to find if you are correct.